Substitutional disorder in the substituted nixantphos ligand C39H32Br0.27Cl0.73NOP2
نویسندگان
چکیده
The structure of 10-(3-bromo/chloro-prop-yl)-4,6-bis-(diphenyl-phosphino)-10H-phenoxazine, C(39)H(32)Br(0.27)Cl(0.73)NOP(2), shows chloro/bromo substitutional disorder in a 3:1 ratio. For application as a ligand in catalysis, the intra-molecular P⋯P distance of 4.263 (2) Å is relevant. The phenoxazine ring system is essentially planar.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008